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I went to use my old PS2 the other night after many years. The controllers thumpads had turned into this sticky, rubbery, goo. Gross. I couldn't play it
Disassemble, clean with isopropyl alcohol, reassemble.
I assume there are guides on youtube.
I cleaned mine with alcohol and it did not help. The material (silicone?) is breaking down so just cleaning it didn't help that much.
https://www.instructables.com/How-to-Clean-Sticky-Rubber/