Those are DOT Hazmat placards for transport, often having a U.N. Number for specific substances (e.g. gasoline is 1203)
NFPA 704 is the multicolor four square thing with numbers in them you might see outside of a business.
Blue = Health,
Red = Flammability,
Yellow = Reactivity,
White = Special (e.g a ~~W~~ indicates reactivity with water)
1 is least hazardous, 4 is most hazardous.