Khoisan languages might be in this category.
https://en.wikipedia.org/wiki/Khoisan_languages
Khoisan languages are best known for their use of click consonants as phonemes. These are typically written with characters such as ǃ and ǂ. Clicks are quite versatile as consonants, as they involve two articulations of the tongue which can operate partially independently. Consequently, the languages with the greatest numbers of consonants in the world are Khoisan. The Juǀʼhoan language has 48 click consonants among nearly as many non-click consonants, strident and pharyngealized vowels, and four tones. The ǃXóõ and ǂHõã languages are even more complex.