A tactical nuke on Kiev would not destroy the value of Ukraine
I agree: the Chernobyl disaster was radiologically worse than a modern nuclear weapon.
I'd raise the problem with using a tactical nuke is the consequences of breaking the nuclear taboo is normalizing use of tactical nukes, and outside of a few morons and sociopaths nobody wants to live in that world.
I guess the bright side would be the "not totally insane or stupid" countries teaming up against a common enemy to do anything possible to remove the people responsible from power. You'd find some extremely well trained and equipped "rebels" hunting heads.